Fired at the muzzle, a representative 5.56 NATO load (4 g, FMJ, 920 m/s) reaches roughly 134 mm (5.3 inches) into polycarbonate. That is enough to defeat a typical barrier of this material — treat anything behind it as exposed.
About Polycarbonate
A polycarbonate pane (~12 mm); true bullet-resistant glass is far thicker and layered.